hm Drac, dunno, there is really no big secret
i start with a letter, duplicate the layer and change the color to the hue i want my outer glow to be
then i blur by 20 (i think)
and then i open curves, choose alpha and have fun with the curve to get the contours
the curves even dont have to look exactly like in the photoshop layerstyles diagrams as you can see
EDIT: actually i did the outer glow in a different way, but that doesnt matter
it works with gaussian blur, just the same i just explained
FYI, i make a selection from alpha, grow (say by 12) and then feather by the same value
i know all of this from a tutorial how to get rounded text:
just blur your text and then apply an alpha curve to your letter until you get a sharp but rounded shape
this link may also be interesting for you:
http://www.mahvin.com/2009/08/gimp-tuto ... affle.html