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Holy cow, I've gotta say this is incredibly impressive, and you've got great strokes going on, especially for using a mouse.
Coupla things, though: (INCOMING WALL OF TEXT)
First, the way your forest fades into the mountains isn't entirely convincing, just because it's so sudden. Mix it up, throw some of the rocky terrain down lower and bring some of the trees up higher. Tree lines on mountains in life have two major elements: where the tall, rich trees stop growing, and then where the shrubbery stops, which is usually a fair ways further up the mountain. Furthermore, tree lines aren't exact, and have a lot to do with where wind is channeled and where things get steeper (ie: the grade of the slope/mountain), rather than just pure elevation. I'm not saying you need to make it more "realistic", but that's the first thing that nags at my eye.
A little further down in the valley, where there are those mountain-esque veins that the trees are on, would be a perfect spot for more rocks. Trees have a really hard time growing on spines like those.
Next, as mentioned above, add more atmosphere! You've clearly established scale with the forest and the trees that get smaller and smaller, so add different atmospheres to differentiate between these. My personal rule of thumb is: things further away have less saturation and are lighter. You can use adjustment layers to do this really quickly if you don't have your work divided into lots of layers within GIMP. You can also take a really soft brush with some white/grey and just brush in atmosphere, but be very subtle.
Last, as I'm interpreting this piece, the trees in the middle/valley are at a lower elevation than the mountains, meaning the only light they'll be catching is light reflected from the sky and the other side of the valley, that the viewer standing on. As it is, you've got light hitting the whole valley, which adds to the depth troubles. (casting most of the valley in shadow will fix a lot of other problems, and it means you can mush out a little and cheat on the tree line because it'll be shadow contrasted against the light of the sun, almost.
Dramatic lighting is also really enticing with the human eye. I'd encourage you to explore and more clearly define your shadow and light in this piece, especially since sunset/sunrise has more shadows and contrast than any other time of day.
Anyhow, great stuff!
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